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Environment and energy

Environment and energy

The complex and spatially heterogeneous nature of degradation in heavily cycled Li-ion cells

Available to watch now, this webinar will explore what the inside of a commercial Li-ion battery looks like after 20,000 cycles

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As service lifetimes of electric vehicle (EV) and grid storage batteries continually improve, it has become increasingly important to understand how Li-ion batteries perform after extensive cycling. Using a combination of spatially resolved synchrotron x-ray diffraction and computed tomography, the complex kinetics and spatially heterogeneous behavior of extensively cycled cells can be mapped and characterized under both near-equilibrium and non-equilibrium conditions.

This webinar shows examples of commercial cells with thousands (even tens of thousands) of cycles over many years. The behaviour of such cells can be surprisingly complex and spatially heterogeneous, requiring a different approach to analysis and modelling than what is typically used in the literature. Using this approach, we investigate the long-term behavior of Ni-rich NMC cells and examine ways to prevent degradation. This work also showcases the incredible durability of single-crystal cathodes, which show very little evidence of mechanical or kinetic degradation after more than 20,000 cycles – the equivalent to driving an EV for 8 million km!

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Toby Bond

Toby Bond is a senior scientist in the Industrial Science group at the Canadian Light Source (CLS), Canada’s national synchrotron facility. He is a specialist in x-ray imaging and diffraction, specializing in in-situ and operando analysis of batteries and fuel cells for industry clients of the CLS. Bond is an electrochemist by training, who completed his MSc and PhD in Jeff Dahn’s laboratory at Dalhousie University with a focus in developing methods and instrumentation to characterize long-term degradation in Li-ion batteries.

 

 

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