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‘Breathing’ crystal reversibly releases oxygen

A new transition-metal oxide crystal that reversibly and repeatedly absorbs and releases oxygen could be ideal for use in fuel cells and as the active medium in clean energy technologies such as thermal transistors, smart windows and new types of batteries. The “breathing” crystal, discovered by scientists at Pusan National University in Korea and Hokkaido University in Japan, is made from strontium, cobalt and iron and contains oxygen vacancies.

Transition-metal oxides boast a huge range of electrical properties that can be tuned all the way from insulating to superconducting. This means they can find applications in areas as diverse as energy storage, catalysis and electronic devices.

Among the different material parameters that can be tuned are the oxygen vacancies. Indeed, ordering these vacancies can produce new structural phases that show much promise for oxygen-driven programmable devices.

Element-specific behaviours

In the new work, a team of researchers led by physicist Hyoungjeen Jeen of Pusan and materials scientist Hiromichi Ohta in Hokkaido studied SrFe0.5Co0.5Ox. The researchers focused on this material, they say, since it belongs to the family of topotactic oxides, which are the main oxides being studied today in solid-state ionics. “However, previous work had not discussed which ion in this compound was catalytically active,” explains Jeen. “What is more, the cobalt-containing topotactic oxides studied so far were fragile and easily fractured during chemical reactions.”

The team succeeded in creating a unique platform from a solid solution of epitaxial SrFe0.5Co0.5O2.5 in which both the cobalt and iron ions bathed in the same chemical environment. “In this way, we were able to test which ion was better for reduction reactions and whether or not it sustained its structural integrity,” Jeen tells Physics World. “We found that our material showed element-specific reduction behaviours and reversible redox reactions.”

The researchers made their material using a pulsed laser deposition technique, ideal for the epitaxial synthesis of multi-element oxides that allowed them to grow SrFe0.5Co0.5O2.5 crystals in which the iron and cobalt ions were randomly located in the crystal. This random arrangement was key to the material’s ability to repeatedly release and absorb oxygen, they say.

“It’s like giving the crystal ‘lungs’ so that it can inhale and exhale oxygen on command,” says Jeen.

Stable and repeatable

This simple breathing picture comes from the difference in the catalytic activity of cobalt and iron in the compound, he explains. Cobalt ions prefer to lose and gain oxygen and these ions are the main sites for the redox activity. However, since iron ions prefer not to lose oxygen during the reduction reaction, they serve as pillars in this architecture. This allows for stable and repeatable oxygen release and uptake.

Until now, most materials that absorb and release oxygen in such a controlled fashion were either too fragile or only functioned at extremely high temperatures. The new material works under more ambient conditions and is stable. “This finding is striking in two ways: only cobalt ions are reduced, and the process leads to the formation of an entirely new and stable crystal structure,” explains Jeen.

The researchers also showed that the material could return to its original form when oxygen was reintroduced, so proving that the process is fully reversible. “This is a major step towards the realization of smart materials that can adjust themselves in real time,” says Ohta. “The potential applications include developing a cathode for intermediate solid oxide fuel cells, an active medium for thermal transistors (devices that can direct heat like electrical switches), smart windows that adjust their heat flow depending on the weather and even new types of batteries.”

Looking ahead, Jeen, Ohta and colleagues aim to investigate the material’s potential for practical applications.

They report their present work in Nature Communications.

New hollow-core fibres break a 40-year limit on light transmission

Optical fibres form the backbone of the Internet, carrying light signals across the globe. But some light is always lost as it travels, becoming attenuated by about 0.14 decibels per kilometre even in the best fibres. That means signals must be amplified every few dozen kilometres – a performance that hasn’t improved in nearly four decades.

Physicists at the University of Southampton, UK have now developed an alternative that could call time on that decades-long lull. Writing in Nature Photonics, they report hollow-core fibres that exhibit 35% less attenuation while transmitting signals 45% faster than standard glass fibres.

“A bit like a soap bubble”

The core of conventional fibres is made of pure glass and is surrounded by a cladding of slightly different glass. Because the core has a higher refractive index than the cladding, light entering the fibre reflects internally, bouncing back and forth in a process known as total internal reflection. This effect traps the light and guides it along the fibre’s length.

The Southampton team led by Francesco Poletti swapped the standard glass core for air. Because air is more transparent than glass, channelling light through it cuts down on scattering and speeds up signals. The problem is that air’s refractive index is lower, so the new fibre can’t use total internal reflection. Instead, Poletti and colleagues guided the light using a mechanism called anti-resonance, which requires the walls of the hollow core to be made from ultra-thin glass membranes.

“It’s a bit like a soap bubble,” Poletti says, explaining that such bubbles appear iridescent because their thin films reflect some wavelengths and lets others through. “We designed our fibre the same way, with glass membranes that reflect light at certain frequencies back into the core.” That anti-resonant reflection, he adds, keeps the light trapped and moving through the fibre’s hollow centre.

Greener telecommunications

To make the new air-core fibre, the researchers stacked thin glass capillaries in a precise pattern, forming a hollow channel in the middle. Heating and drawing the stack into a hair-thin filament preserved this pattern on a microscopic scale. The finished fibre has a nested design: an air core surrounded by ultra-thin layers that provide anti-resonant guidance and cut down on leakage.

To test their design, the team measured transmission through a full spool of fibre, then cut the fibre shorter and compared the results. They also fired in light pulses and tracked the echoes. Their results show that the hollow fibres reduce attenuation to just 0.091 decibels per kilometre. This lower loss implies that fewer amplifiers would be needed in long cables, lowering costs and energy use. “There’s big potential for greener telecommunications when using our fibres,” says Poletti.

Poletti adds that reduced attenuation (and thus lower energy use) is only one of the new fibre’s advantages. At the 0.14 dB/km attenuation benchmark, the new hollow fibre supports a bandwidth of 54 THz compared to 10 THz for a normal fibre. At the reduced 0.1 dB/km attenuation, the bandwidth is still 18 THz, which is close to twice that of a normal cable. This means that a single strand can carry far more channels at once.

Perhaps the most impressive advantage is that because the speed of light is faster in air than in glass, data could travel the same distance up to 45% faster. “It’s almost the same speed light takes when we look at a distant star,” Poletti says. The resulting drop in latency, he adds, could be crucial for real-time services like online gaming or remote surgery, and could also speed up computing tasks such as training large language models.

Field testing

As well as the team’s laboratory tests, Microsoft has begun testing the fibres in real systems, installing segments in its network and sending live traffic through them. These trials prove the hollow-core design works with existing telecom equipment, opening the door to gradual rollout. In the longer run, adapting amplifiers and other gear that are currently tuned for solid glass fibres could unlock even better performance.

Poletti believes the team’s new fibres could one day replace existing undersea cables. “I’ve been working on this technology for more than 20 years,” he says, adding that over that time, scepticism has given way to momentum, especially now with Microsoft as an industry partner. But scaling up remains a real hurdle. Making short, flawless samples is one thing; mass-producing thousands of kilometres at low cost is another. The Southampton team is now refining the design and pushing toward large-scale manufacturing. They’re hopeful that improvements could slash losses by another order of magnitude and that the anti-resonant design can be tuned to different frequency bands, including those suited to new, more efficient amplifiers.

Other experts agree the advance marks a turning point. “The work builds on decades of effort to understand and perfect hollow-core fibres,” says John Ballato, whose group at Clemson University in the US develops fibres with specialty cores for high-energy laser and biomedical applications. While Ballato notes that such fibres have been used commercially in shorter-distance communications “for some years now”, he believes this work will open them up to long-haul networks.

Indefinite causal order: how quantum physics is challenging our understanding of cause and effect

The concept of cause and effect plays an important role in both our everyday lives, and in physics. If you set a ball down in front of a window and kick it hard, a split-second later the ball will hit the window and smash it. What we don’t observe is a world where the window smashes on its own, thereby causing the ball to be kicked – that would seem rather nonsensical. In other words, kick before smash, and smash before kick, are two different physical processes each having a unique and definite causal order.

But, does definite causal order also reign supreme in the quantum world, where concepts like position and time can be fuzzy?  Most physicists are happy to accept the paradox of Schrödinger’s cat – a thought experiment in which a cat hidden in a box is simultaneously dead and alive at the same time, until you open the box to check. Schrödinger’s cat illustrates the quantum concept of “superposition”, whereby a system can be in two or more states at the same time. It is only when a measurement is made (by opening the box), does the system collapse into one of its possible states.

But could two (or more) causally distinct processes occur at the same time in the quantum world? The answer, perhaps shockingly, is yes and this paradoxical phenomenon is called indefinite causal order (ICO).

Stellar superpositions and the order of time

It turns out that different causal processes can also exist in a superposition. One example is a thought experiment called the “gravitational quantum switch”, which was proposed in 2019 by Magdalena Zych of the University of Queensland and colleagues (Nat. Comms 10 3772). This features our favourite quantum observers Alice and Bob, who are in the vicinity of a very large mass, such as a star. Alice and Bob both have initially synchronized clocks and in the quantum world, these clocks would continue to run at identical rates. However, Einstein’s general theory of relativity dictates that the flow of time is influenced by the distribution of matter in the vicinity of Alice and Bob. This means that if Alice is closer to the star than Bob, then her clock will run slower than Bob’s, and vice versa.

Like with Schrödinger’s cat, quantum mechanics allows the star to be in a superposition of spatial states; meaning that in one state Alice is closer to the star than Bob, and in the other Bob is closer to the star than Alice. In other words, this is a superposition of a state in which Alice’s clock runs slower than Bob’s, and a state in which Bob’s clock runs slower than Alice’s.

Alice and Bob are both told they will receive a message at a specific time (say noon) and that they would then pass that message on to the their counterpart. If Alice’s clock is running faster than Bob’s then she will receive the message first, and then pass it on to Bob, and vice versa. This superposition of Alice to Bob with Bob to Alice is an example of indefinite causal order.

Now, you might be thinking “so what” because this seems to be a trivial example. But it becomes more interesting if you replace the message with a quantum particle like a photon; and have Alice and Bob perform different operations on that photon. If the two operations do not commute – such as rotations of the photon polarization in the X and Z planes – then the order in which the operations are done will affect the outcome.

As a result, this “gravitational quantum switch” is a superposition of two different causal processes with two different outcomes. This means that Alice and Bob could do more exotic operations on the photon, such as “measure-and-reprepare” operations (where a quantum system is first measured, and then, based on the measurement outcome, a new quantum state is prepared). In this case Alice measures the quantum state of the received photon and prepares a photon that she sends to Bob (or vice versa).

Much like Schrödinger’s cat, a gravitational quantum switch cannot currently be realized in the lab. But, never say never. Physicists have been able to create experimental analogues of some thought experiments, so who knows what the future will bring. Indeed, a gravitational quantum switch could provide important information regarding a quantum description of gravity – something that has eluded physicists ever since quantum mechanics and general relativity were being developed in the early 20th century.

Switches and superpositions

Moving on to more practical ICO experiments, physicists have already built and tested light-based quantum switches in the lab. Instead of having the position of the star determining whether Alice or Bob go first, the causal order is determined by a two-level quantum state – which can have a value of 0 or 1. If this control state is 0, then Alice goes first and if the control state is 1, then Bob goes first. Crucially, when the control state is in a superposition of 0 and 1 the system shows indefinite causal order (see figure 1).

1 Simultaneous paths

Illustration of a proton travelling between Alice and Bob on different routes

In this illustration of a quantum switch a photon (driving a car) can follow two different paths, each with a different causal order. One path (top) leads to Alice’s garage followed by a visit to Bob’s drive thru. The second path (middle) visits Bob first, and then Alice. The path taken by the photon is determined by a control qubit that is represented by a traffic light. If the value of the qubit is “0” then the photon visits Alice First; if the qubit is “1” then the photon visits Bob first. Both of these scenarios have definite causal order.

However, the control qubit can exist in a quantum superposition of “0” and “1” (bottom). In this superposition, the path followed by the photon – and therefore the temporal order in which it visits Alice and Bob – is not defined. This is an example of indefinite causal order. Of course, any attempt to identify exactly which path the photon goes through initially will destroy the superposition (and therefore the ICO) and the photon will take only one definite path.

The first such quantum switch was created by in 2015 by Lorenzo Procopio (now at Germany’s University of Paderborn) and colleagues at the Vienna Center for Quantum Science and Technology (Nat. Comms 6, 7913). Their quantum switch involves firing a photon at a beam splitter, which puts the photon into a superposition of a photon that has travelled straight through the splitter (state 0) and a photon that has been deflected by 90 degrees (state 1). This spatial superposition is the control state of the quantum switch, playing the role of the star in the gravitational quantum switch.

State 0 photons first travel to an Alice apparatus where a polarization rotation is done in a specific direction (say X). Then the photons are sent to a Bob apparatus where a non-commuting rotation (say Z) is done. Conversely, the photons that travel along the state 1 path encounter Bob before Alice.

Finally, the state 0 and state 1 paths are recombined at a second beamsplitter, which is monitored by two photon-detectors. Because Alice-then-Bob has a different effect on a photon than does Bob-then-Alice, interference can occur between recombined photons. This interference is studied by systematically changing certain aspects of the experiment. For example, by changing Alice’s direction of rotation or the polarization of the incoming photons.

In 2017 quantum-information researcher Giulia Rubino, then at the Vienna Center for Quantum Science and Technology, teamed up with Procopia and colleagues to verify ICO in their quantum switch using a “causal witness” (Sci. Adv. 3 e1602589). This involves doing a specific set of experiments on the quantum switch and calculating a mathematical entity (the causal witness) that reveals whether a system has definite or indefinite causal order. Sure enough, this test revealed that their system does indeed have ICO. Since then, physicists working in several independent labs have successfully created their own quantum switches.

Computational speed up?

While this effect might still seem somewhat obscure, in 2019, an international team led by the renowned Chinese physicist Jian-Wei Pan showed that a quantum switch can be very useful for doing computations that are distributed between two parties (Phys. Rev. Lett122 120504). In such a scenario a string of data is received and then processed by Alice, who then passes the results on to Bob for further processing. In an experiment using photons, they showed that ICO delivers an exponential speed-up of the rate at which longer strings are processed – compared to a system with no ICO.

Physicists are also exploring if ICO could be used to enhance quantum metrology. Indeed, recent calculations by Oxford University’s Giulio Chiribella and colleagues suggest that it could lead to a significant increase in precision when compared to techniques that involve states with definite causal order (Phys. Rev. Lett. 124 190503).

While other applications could be possible, it is often difficult to work out whether ICO offers the best solution to a specific problem. For example, physicists had thought a quantum switch offered an advantage when it comes to communicating along a noisy channel, but it turns out that some configurations of Alice and Bob with definite causal order were just as good as an ICO.

Beyond the quantum switch, there are other types of circuits that would display ICO. These include “quantum circuits with quantum control of causal order”, which have yet to be implemented in the lab because of their complexity.

But despite the challenges in creating ICO systems and proving that they outperform other solutions, it looks like ICO is set to join ranks of other weird phenomena such as superposition and entanglement that have found practical applications in quantum technologies.

This article forms part of Physics World‘s contribution to the 2025 International Year of Quantum Science and Technology (IYQ), which aims to raise global awareness of quantum physics and its applications.

Stayed tuned to Physics World and our international partners throughout the year for more coverage of the IYQ.

Find out more on our quantum channel.

Reformulation of general relativity brings it closer to Newtonian physics

The first-ever detection of gravitational waves was made by LIGO in 2015 and since then researchers have been trying to understand the physics of the black-hole and neutron-star mergers that create the waves. However, the physics is very complicated and is defined by Albert Einstein’s general theory of relativity.

Now Jiaxi Wu, Siddharth Boyeneni and Elias Most at the California Institute of Technology (Caltech) have addressed this challenge by developing a new formulation of general relativity that is inspired by the equations that describe electromagnetic interactions. They show that general relativity behaves in the same way as the gravitational inverse square law described by Isaac Newton more than 300 years ago. “This is a very non-trivial insight,” says Most.

One of the fascinations of black holes is the extreme physics they invoke. These astronomical objects  pack so much mass into so little space that not even light can escape their gravitational pull. Black holes (and neutron stars) can exist in binary systems in which the objects orbit each other. These pairs eventually merge to create single black holes in events that create detectable gravitational waves. The study of these waves provides an important testbed for gravitational physics. However, the mathematics of general relativity that describe these mergers is very complicated.

Inverse square law

According to Newtonian physics, the gravitational attraction between two masses is proportional to the inverse of the square of the distance between them – the inverse square law. However, as Most points out, “Unless in special cases, general relativity was not thought to act in the same way.”

Over the past decade, gravitational-wave researchers have taken various approaches including post-Newtonian theory and effective one-body approaches to better understand the physics of black-hole mergers. One important challenge is how to model parameters such as orbital eccentricity and precession in black hole systems and how best to understand “ringdown”. The latter is the process whereby a black hole formed by a merger emits gravitational waves as it relaxes into a stable state.

The trio’s recasting of the equations of general relativity was inspired by the Maxwell equations that describe how electric and magnetic fields leapfrog each other through space. According to these equations, the forces between electric charges diminish according to the same inverse square law as Newton’s gravitational attraction.

Early reformulations

The original reformulations of “gravitoelectromagnetism” date back to the 90s. Most explains how among those who did this early work was his Caltech colleague and LIGO Nobel laureate Kip Thorne, who exploited a special mathematical structure of the curvature of space–time.

“This structure mathematically looks like the equations governing light and the attraction of electric charges, but the physics is quite different,” Most tells Physics World. The gravito-electric field thus derived describes how an object might squish under the forces of gravity. “Mathematically this means that the previous gravito-electric field falls off with inverse distance cubed, which is unlike the inverse distance square law of Newtonian gravity or electrostatic attraction,” adds Most.

Most’s own work follows on from previous studies of the potential radio emission from the interaction of magnetic fields during the collision of neutron stars and black holes from which it seemed reasonable to then “think about whether some of these insights naturally carry over to Einstein’s theory of gravity”. The trio began with different formulations of general relativity and electromagnetism with the aim of deriving gravitational analogues for the electric and magnetic fields that behave more closely to classical theories of electromagnetism. They then demonstrated how their formulation might describe the behaviour of a non-rotating Schwarzschild black hole, as well as a black hole binary.

Not so different

“Our work says that actually general relativity is not so different from Newtonian gravity (or better, electric forces) when expressed in the right way,” explains Most. The actual behaviour predicted is the same in both formulations but the trio’s reformulation reveals how general relativity and Newtonian physics are more similar than they are generally considered to be. “The main new thing is then what does it mean to ‘observe’ gravity, and what does it mean to measure distances relative to how you ‘observe’.”

Alexander Phillipov is a black-hole expert at the University of Maryland in the US and was not directly involved with Most’s research. He describes the research as “very nice”, adding that while the analogy between gravity and electromagnetism has been extensively explored in the past, there is novelty in the interpretation of results from fully nonlinear general relativistic simulations in terms of effective electromagnetic fields. “It promises to provide valuable intuition for a broad class of problems involving compact object mergers.”

The research is described in Physical Review Letters.

Researchers create glow-in-the-dark succulents that recharge with sunlight

“Picture the world of Avatar, where glowing plants light up an entire ecosystem,” describes Shuting Liu of South China Agricultural University in Guangzhou.

Well, that vision is now a step closer thanks to researchers in China who have created glow-in-the-dark succulents that recharge in sunlight.

Instead of coaxing cells to glow through genetic modification, the team instead used afterglow phosphor particles – materials similar to those found in glow-in-the-dark toys – that can absorb light and release it slowly over time.

The researchers then injected the particles into succulents, finding that they produced a strong glow, thanks to the narrow, uniform and evenly distributed channels within the leaf that helped to disperse the particles.

After a couple of minutes of exposure to sunlight or indoor LED light, the modified plants glowed for up to two hours. By using different types of phosphors, the researchers created plants that shine in various colours, including green, red and blue.

The team even built a glowing plant wall with 56 succulents, which was bright enough to illuminate nearby objects.

“I just find it incredible that an entirely human-made, micro-scale material can come together so seamlessly with the natural structure of a plant,” notes Liu. “The way they integrate is almost magical. It creates a special kind of functionality.”

Big data helps Gaelic football club achieve promotion following 135-year wait

An astrophysics PhD student from County Armagh in Northern Ireland has combined his passion for science with Gaelic football to help his club achieve a historic promotion.

Eamon McGleenan plays for his local team – O’Connell’s GAC Tullysaran – and is a PhD student at Queen’s University Belfast, where he is a member of the Predictive Sports Analytics (PSA) research team, which was established in 2023.

McGleenan and his PhD supervisor David Jess teamed up with GAC Tullysaran to investigate whether data analysis and statistical techniques could improve their training and results.

Over five months, the Queen’s University researchers took over 550 million individual measurements from the squad, which included information such as player running speed, accelerations and heart rates.

“We applied mathematical models to the big data we obtained from the athletes,” notes McGleenan. “This allowed us to examine how the athletes evolved over time and we then provided key insights for the coaching staff, who then generated bespoke training routines and match tactics.”

The efforts immediately paid off as in July GAC Tullysaran won their league by two points and were promoted for the first time in 135 years to the top-flight Senior Football League, which they will start in March.

“The statistical insight provided by PSA is of great use and I like how it lets me get the balance of training right, especially in the run-up to match day,” noted Tullysaran manager Pauric McGlone, who adds that it also provided a bit of competition in the squad that ensured the players were “conditioned in a way that allows them to perform at their best”.

For more about the PSA’s activities, see here.

Zero-point motion of atoms measured directly for the first time

Physicists in Germany say they have measured the correlated behaviour of atoms in molecules prepared in their lowest quantum energy state for the first time. Using a technique known as Coulomb explosion imaging, they showed that the atoms do not simply vibrate individually. Instead, they move in a coupled fashion that displays fixed patterns.

According to classical physics, molecules with no thermal energy – for example, those held at absolute zero – should not move. However, according to quantum theory, the atoms making up these molecules are never completely “frozen”, so they should exhibit some motion even at this chilly temperature. This motion comes from the atoms’ zero-point energy, which is the minimum energy allowed by quantum mechanics for atoms in their ground state at absolute zero. It is therefore known as zero-point motion.

Reconstructing the molecule’s original structure

To study this motion, a team led by Till Jahnke from the Institute for Nuclear Physics at Goethe University Frankfurt and the Max Planck Institute for Nuclear Physics in Heidelberg used the European XFEL in Hamburg to bombard their sample – an iodopyridine molecule consisting of 11 atoms – with ultrashort, high-intensity X-ray pulses. These high-intensity pulses violently eject electrons out of the iodopyridine, causing its constituent atoms to become positively charged (and thus to repel each other) so rapidly that the molecule essentially explodes.

To image the molecular fragments generated by the explosion, the researchers used a customized version of a COLTRIMS reaction microscope. This approach allowed them to reconstruct the molecule’s original structure.

From this reconstruction, the researchers were able to show that the atoms do not simply vibrate individually, but that they do so in correlated, coordinated patterns. “This is known, of course, from quantum chemistry, but it had so far not been measured in a molecule consisting of so many atoms,” Jahnke explains.

Data challenges

One of the biggest challenges Jahnke and colleagues faced was interpreting what the microscope data was telling them. “The dataset we obtained is super-rich in information and we had already recorded it in 2019 when we began our project,” he says. “It took us more than two years to understand that we were seeing something as subtle (and fundamental) as ground-state fluctuations.”

Since the technique provides detailed information that is hidden to other imaging approaches, such as crystallography, the researchers are now using it to perform further time-resolved studies – for example, of photochemical reactions. Indeed, they performed and published the first measurements of this type at the beginning of 2025, while the current study (which is published in Science) was undergoing peer review.

“We have pushed the boundaries of the current state-of-the-art of this measurement approach,” Jahnke tells Physics World, “and it is nice to have seen a fundamental process directly at work.”

For theoretical condensed matter physicist Asaad Sakhel at Balqa Applied University, Jordan, who was not involved in this study, the new work is “an outstanding achievement”. “Being able to actually ‘see’ zero-point motion allows us to delve deeper into the mysteries of quantum mechanics in our quest to a further understanding of its foundations,” he says.

Artificial intelligence predicts future directions in quantum science

Can artificial intelligence predict future research directions in quantum science? Listen to this episode of the Physics World Weekly podcast to discover what is already possible.

My guests are Mario Krenn – who heads the Artificial Scientist Lab at Germany’s Max Planck Institute for the Science of Light – and Felix Frohnert, who is doing a PhD on the intersection of quantum physics and machine learning at Leiden University in the Netherlands.

Frohnert, Krenn and colleagues published a paper earlier this year called “Discovering emergent connections in quantum physics research via dynamic word embeddings” in which they analysed more than 66,000 abstracts from the quantum-research literature to see if they could predict future trends in the field. They were particularly interested in the emergence of connections between previously isolated subfields of quantum science.

We chat about what motivated the duo to use machine learning to study quantum science; how their prediction system works; and I ask them whether they have been able to predict current trends in quantum science using historical data.

Their paper appears in the journal Machine Learning Science and Technology. It is published by IOP Publishing – which also brings you Physics World.  Krenn is on the editorial board of the journal and in the podcast he explains why it is important to have a platform to publish research at the intersection of physics and machine learning.

This article forms part of Physics World‘s contribution to the 2025 International Year of Quantum Science and Technology (IYQ), which aims to raise global awareness of quantum physics and its applications.

Stayed tuned to Physics World and our international partners throughout the next 12 months for more coverage of the IYQ.

Find out more on our quantum channel.

 

Errors in A-level physics papers could jeopardize student university admissions, Institute of Physics warns

Errors in some of this year’s A-level physics exam papers could leave students without good enough grades to study physics at university. The mistakes have forced Tom Grinyer, chief executive of the Institute of Physics (IOP), to write to all heads of physics at UK universities, calling on them to “take these exceptional circumstances into account during the final admissions process”. The IOP is particularly concerned about students whose grades are lower than expected or are “a significant outlier” compared to other subjects.

The mistakes in question appeared in the physics (A) exam papers 1 and 2 set by the OCR exam board. Erratum notices had been issued to students at the start of the exam in June, but a further error in paper 2 was only spotted after the exam had taken place, causing some students to get stuck. Physics paper 2 from the rival AQA exam board was also seen to contain complex phrasing that hindered students’ ability to answer the question and led to time pressures.

A small survey of physics teachers carried out after the exam by the IOP, which publishes Physics World, reveals that 41% were dissatisfied with the OCR physics exam papers and more than half (58%) felt that students had a negative experience. Two-thirds of teachers, meanwhile, reported that students had a negative experience during the AQA exam. A-levels are mostly taken by 18 year olds in England, Wales and Northern Ireland, with the grades being used by universities to decide admission.

Grinyer says that the IOP is engaging in “regular, open dialogue with exam boards” to ensure that the assessment process supports and encourages students, while maintaining the rigour and integrity of the qualification. “Our immediate concern,” Grinyer warns, “is that the usual standardization processes and adjustments to grade boundaries – particularly for the OCR paper with errors – may fail to compensate fully for the negative effect on exam performance for some individuals.”

An OCR spokesperson told Physics World that the exam board is “sorry to the physics students and teachers affected by errors in A-level physics this year”. The board says that it “evaluated student performance across all physics papers, and took all necessary steps to mitigate the impact of these errors”. The OCR claims that the 13,000 students who sat OCR A-level physics A this year “can be confident” in their A-level physics results.

“We have taken immediate steps to review and strengthen our quality assurance processes to prevent such issues from occurring in the future,” the OCR adds. “We appreciated the opportunity to meet with the Institute of Physics to discuss these issues, and also to discuss our shared interest in encouraging the growth of this vital subject.”

Almost 23,500 students sat AQA A-level physics this year and an AQA spokesperson told Physics World that the exam board “listened to feedback and took steps to make A-level physics more accessible” to students and that there “is no need for universities to make an exception for AQA physics outcomes when it comes to admissions criteria”.

“These exam papers were error-free, as teachers and students would expect, and we know that students found the papers this year to be more accessible than last year,” they say. “We’ll continue to engage with any feedback that we receive, including feedback from the Institute of Physics, to explore how we can enhance our A-level physics assessments and give students the best possible experience when they sit exams.”

Students ‘in tears’

The IOP now wants A-level physics students to be given a “fair opportunity” when it comes to university admissions. “These issues are particularly concerning for students on widening participation pathways, many of whom already face structural barriers to high-stakes assessment,” the IOP letter states. “The added challenge of inaccessible or error-prone exam papers risks compounding disadvantage and may not reflect the true potential of these students.”

The IOP also contacted AQA last year over inaccessible contexts and language used in previous physics exams. But despite AQA’s assurances that the problems would be addressed, some of the same issues have now recurred. Helen Sinclair, head of physics at the all-girls Wimbledon High School, believes that the “variable quality” of recent A-level papers have had “far-reaching consequences” on young people thinking of going into physics at university.

“Our students have exceptionally high standards for themselves and the opaque nature of many questions affects them deeply, no matter what grades they ultimately achieve. This has even led some to choose to apply for other subjects at university,” she told Physics World. “This is not to say that papers should not be challenging; however, better scaffolding within some questions would help students anchor themselves in what is an already stressful environment, and would ultimately enable them to better demonstrate their full potential within an exam.”

Students come out of the exams feeling disheartened, and those students share their perceptions with younger students

Abbie Hope, Stokesley School

Those concerns are echoed by Abbie Hope, head of physics at Stokesley School near Middlesbrough. She says the errors in this year’s exam papers are “not acceptable” and believes that OCR has “failed their students”. Hope says that AQA physics papers in recent years have been “very challenging” and have resulted in students feeling like they cannot do physics. She also says some have emerged from exam halls in tears.

“Students come out of the exams feeling disheartened and share their perceptions with younger students,” she says. “I would rather students sat a more accessible paper, with higher grade boundaries so they feel more successful when leaving the exam hall, rather than convinced they have underachieved and then getting a surprise on results day.” Hope fears the mistakes will undermine efforts to encourage uptake and participation in physics and that exam boards need to serve students and teachers better.

A ‘growing unease’

Rachael Houchin, head of physics at Royal Grammar School Newcastle, says this year’s errors have added to her “growing unease” about the state of physics education in the UK. “Such incidents – particularly when they are public and recurring – do little to improve the perception of the subject or encourage its uptake,” she says. “Everyone involved in physics education – at any level – has a duty to get it right. If we fail, we risk physics drifting into the category of subjects taught predominantly in selective or independent schools, and increasingly absent from the mainstream.”

Hari Rentala, associate director of education and workforce at the IOP, is concerned that the errors unfairly “perpetuate the myth” that physics is a difficult subject. “OCR appear to have managed the situation as best they can, but this is not much consolation for how students will have felt during the exam and over the ensuing weeks,” says Rentala. “Once again AQA set some questions that were overly challenging. We can only hope that the majority of students who had a negative experience as a result of these issues at least receive a fair grade – as grade boundaries have been adjusted down.”

Mixed news for pupils

Despite the problems with some specific papers, almost 45,000 students took A-level physics in the UK – a rise of 4.3% on last year – to reach the highest level for 25 years. Physics is now the sixth most popular subject at A-level, up from ninth last year, with girls representing a quarter of all candidates. Meanwhile, in Scotland the number of entries in both National 5 and Higher physics was 13,680 and 8560, respectively, up from 13,355 and 8065 last year.

“We are delighted so many young people, and increasing numbers of girls, are hearing the message that physics can open up a lifetime of opportunities,” says Grinyer. “If we can build on this momentum there is a real opportunity to finally close the gap between boys and girls in physics at A-level. To do that we need to continue to challenge the stereotypes that still put too many young people off physics and ensure every young person knows that physics – and a career in science and innovation – could be for them.”

However, there is less good news for younger pupils, with a new IOP report finding that more than half a million GCSE students are expected to start the new school year with no physics teacher. It reveals that a quarter of English state schools have no specialist physics teachers at all and fears that more than 12,000 students could miss out on taking A-level physics because of this. The IOP wants the UK government to invest £120m over the next 10 years to address the shortage by retaining, recruiting and retraining a new generation of physics teachers.

Quantum sensors reveal ‘smoking gun’ of superconductivity in pressurized bilayer nickelates

Physicists at the Chinese Academy of Sciences (CAS) have used diamond-based quantum sensors to uncover what they say is the first unambiguous experimental evidence for the Meissner effect – a hallmark of superconductivity – in bilayer nickelate materials at high pressures. The discovery could spur the development of highly sensitive quantum detectors that can be operated under high-pressure conditions.

Superconductors are materials that conduct electricity without resistance when cooled to below a certain critical transition temperature Tc. Apart from a sharp drop in electrical resistance, another important sign that a material has crossed this threshold is the appearance of the Meissner effect, in which the material expels a magnetic field from its interior (diamagnetism). This expulsion creates such a strong repulsive force that a magnet placed atop the superconducting material will levitate above it.

In “conventional” superconductors such as solid mercury, the Tc is so low that the materials must be cooled with liquid helium to keep them in the superconducting state. In the late 1980s, however, physicists discovered a new class of superconductors that have a Tabove the boiling point of liquid nitrogen (77 K). These “unconventional” or high-temperature superconductors are derived not from metals but from insulators containing copper oxides (cuprates).

Since then, the search has been on for materials that superconduct at still higher temperatures, and perhaps even at room temperature. Discovering such materials would have massive implications for technologies ranging from magnetic resonance imaging machines to electricity transmission lines.

Enter nickel oxides

In 2019 researchers at Stanford University in the US identified nickel oxides (nickelates) as additional high-temperature superconductors. This created a flurry of interest in the superconductivity community because these materials appear to superconduct in a way that differs from their copper-oxide cousins.

Among the nickelates studied, La3Ni2O7-δ (where δ can range from 0 to 0.04) is considered particularly promising because in 2023, researchers led by Meng Wang of China’s Sun Yat-Sen University spotted certain signatures of superconductivity at a temperature of around 80 K. However, these signatures only appeared when crystals of the material were placed in a device called a diamond anvil cell (DAC). This device subjects samples of material to extreme pressures of more than 400 GPa (or 4 × 106 atmospheres) as it squeezes them between the flattened tips of two tiny, gem-grade diamond crystals.

The problem, explains Xiaohui Yu of the CAS’ Institute of Physics, is that it is not easy to spot the Meissner effect under such high pressures. This is because the structure of the DAC limits the available sample volume and hinders the use of highly sensitive magnetic measurement techniques such as SQUID. Another problem is that the sample used in the 2023 study contains several competing phases that could mix and degrade the signal of the La3Ni2O7-δ.

Nitrogen-vacancy centres embedded as in-situ quantum sensors

In the new work, Yu and colleagues used nitrogen-vacancy (NV) centres embedded in the DAC as in-situ quantum sensors to track and image the Meissner effect in pressurized bilayer La3Ni2O7-δ. This newly developed magnetic sensing technique boasts both high sensitivity and high spatial resolution, Yu says. What is more, it fits perfectly into the DAC high-pressure chamber.

Next, they applied a small external magnetic field of around 120 G. Under these conditions, they measured the optically detected magnetic resonance (ODMR) spectra of the NV centres point by point. They could then extract the local magnetic field from the resonance frequencies of these spectra. “We directly mapped the Meissner effect of the bilayer nickelate samples,” Yu says, noting that the team’s image of the magnetic field clearly shows both a diamagnetic region and a region where magnetic flux is concentrated.

Weak demagnetization signal

The researchers began their project in late 2023, shortly after receiving single-crystal samples of La3Ni2O7-δ from Wang. “However, after two months of collecting data, we still had no meaningful results,” Yu recalls. “From these experiments, we learnt that the demagnetization signal in La3Ni2O7-δ crystals was quite weak and that we needed to improve either the nickelate sample or the sensitivity of the quantum sensor.”

To overcome these problems, they switched to using polycrystalline samples, enhancing the quality of the nickelate samples by doping them with praseodymium to make La2PrNi2O7. This produced a sample with an almost pure bilayer structure and thus a much stronger demagnetization signal. They also used shallow NV centres implanted on the DAC cutlet (the smaller face of the two diamond tips).

“Unlike the NV centres in the original experiments, which were randomly distributed in the pressure-transmitting medium and have relatively large ODMR widths, leading to only moderate sensitivity in the measurements, these shallow centres are evenly distributed and well aligned, making it easier for us to perform magnetic imaging with increased sensitivity,” Yu explains.

These improvements enabled the team to obtain a demagnetization signal from the La2PrNi2O7 and La3Ni2O7-δ samples, he tells Physics World. “We found that the diamagnetic signal from the La2PrNi2O7 samples is about five times stronger than that from the La3Ni2O7-δ ones prepared under similar conditions – a result that is consistent with the fact that the Pr-doped samples are of a better quality.”

Physicist Jun Zhao of Fudan University, China, who was not involved in this work, says that Yu and colleagues’ measurement represents “an important step forward” in nickelate research. “Such measurements are technically very challenging, and their success demonstrates both experimental ingenuity and scientific significance,” he says. “More broadly, their result strengthens the case for pressurized nickelates as a new platform to study high-temperature superconductivity beyond the cuprates. It will certainly stimulate further efforts to unravel the microscopic pairing mechanism.”

As well as allowing for the precise sensing of magnetic fields, NV centres can also be used to accurately measure many other physical quantities that are difficult to measure under high pressure, such as strain and temperature distribution. Yu and colleagues say they are therefore looking to further expand the application of these structures for use as quantum sensors in high-pressure sensing.

They report their current work in National Science Review.

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