By combining a band-structure engineered multi-quantum-well heterostructure with a nanostructure known as a metasurface, physicists in Austria and the US have created a device that can efficiently transform light into different frequencies – including those at technologically important near-infrared wavelengths. Their technique, which boosts nonlinear frequency conversion, could help in the development of smaller and more efficient components for telecommunications, quantum information transfer and other photonics technologies.
Nonlinear frequency conversion is an optical process in which a material is used to generate light of a different frequency to that incident on the material. It is now routinely employed in a wide range of photonics devices that rely on frequency mixing, ultrafast signal processing, broadband and pulsed light sources, and high-speed light modulation. It is also used to generate entangled photon pairs for quantum communication. One common type of frequency conversion, and the one used in this new study, is second-harmonic generation. Here, two input photons are combined to produce one photon with twice the energy.
Efficient nonlinear devices require light with high electric field strengths and materials that respond to these intense electromagnetic fields by producing a light polarization that is not directly proportional to the applied field. “Only a handful of such nonlinear crystals exist and these have complicated structures with weak nonlinearities, which means they require high optical powers to make photons interact with each other,” says Marcus Ossiander from the Institute of Experimental Physics at TU Graz in Austria, one of the authors of the new study published in Nature Nanotechnology. “While, new such crystals emerge from time to time, their structure is fixed, which dictates which light wavelengths they work at and how efficiently.”
Asymmetrically coupled multi-quantum wells
Recently, a group of researchers at the University of Texas at Austin in the US, led by Seth Bank, also an author of this latest study, succeeded in creating an optical nonlinearity not via a new crystal structure but by growing a semiconductor metamaterial made from nanoscale layers of gallium arsenide and aluminium gallium arsenide. These layers contain multiple quantum wells that are asymmetrically coupled to each other.
The quantum wells confine electrons in one dimension while allowing them to move freely in the other two dimensions, something that has the effect of restricting their energy levels into discrete, quantum states. Since they are asymmetrically coupled, the electrons end up mainly moving in one direction when exposed to light. This so-called “one-way street leads to increased nonlinear electron oscillations, allowing light waves to interact with each other extremely efficiently and exceed naturally occurring nonlinearities.
Ossiander and his colleagues, including Federico Capasso at the Harvard John A. Paulson School of Engineering and Applied Sciences (SEAS), have now added a second, two-dimensional metamaterial atop the first one. This metasurface, which consists of titanium dioxide pillars, each several hundred nanometres in size, precisely creates the particular light polarization required to deflect incoming light so that it scatters along the one-way street. This enhances the interactions between light waves even further and so increases the intensity of light in the structure.
An extra lap
Researchers have known for a while now that metasurfaces are extremely good at resonantly trapping light and increasing the interaction of light with matter. Usually, the process is straightforward, explains first author Pernille Undrum Fathi, who works in Capasso’s group: you implement a resonant metasurface, and it enhances, for example, the nonlinear effects that you are aiming for.
“The new material sent us for an extra lap, however, because, during our experiments, we discovered that the designable second-order nonlinear susceptibility tensor element (the required incident polarization) is different to that of conventional materials,” she says. “Therefore, when we shone light at exactly normal incidence, the metasurface–material combination generated light waves whose polarizations cancelled each other out completely, so annihilating any enhanced optical nonlinearity.”
However, the researchers found that tilting the sample by just 0.3° broke this symmetry and solved this challenge. Indeed, they were able to increase the effective nonlinear conversion of the light to three orders of magnitude higher than that for a non-patterned heterostructure. The effect is also higher than previously reported values for comparable devices at near‑infrared wavelengths.
“Nonlinear optics are ubiquitous in modern science and technology, with examples including the generation of light at new frequencies (where lasers might be unavailable), all-optical signal processing and the generation of entangled photon pairs for quantum communication,” Ossiander tells Physics World. “Enhancing the fundamental processes enabling this technology will allow for much more efficient, compact devices and enable new measurements that would previously be impossible.”
Nonlinear optics: we explore the science and its many applications
Metasurfaces offer an excellent route to control and enhance the interaction of light with matter, and the team was intrigued to find out what could be made possible when combining these materials with nanostructures, adds Fathi.
“Working with new materials of course comes with additional uncertainty, and we spent a lot of time learning about and understanding the mechanisms of these new structures and how the particular nonlinear tensor elements of this material interact with the resonant modes introduced by the metasurface,” she says.
“The material we studied is very interesting but also complex,” adds Ossiander, noting that the reseachers believe they can learn how to make even better use of the designer nonlinearity in it by further investigating its fundamental properties. “Indeed, there is a new publication in Optica by Bank’s group on how to improve the multi-quantum-well material even more.”
