Physicists in the US have found an explanation for why electrons in a material called pentalayer moiré graphene carry fractional charges even in the absence of a magnetic field. This phenomenon is known as the fractional quantum anomalous Hall effect, and teams at the Massachusetts Institute of Technology (MIT), Johns Hopkins University and Harvard University/University of California, Berkeley have independently suggested that an interaction-induced topological “flat” band in the material’s electronic structure may be responsible.
Scientists already knew that electrons in graphene could, in effect, split into fractions of themselves in the presence of a very strong magnetic field. This is an example of the fractional quantum Hall effect, which occurs when a material’s Hall conductance is quantized at fractional multiples of e2/h.
In 2023, several teams of researchers introduced a new twist by observing this fractional quantization even without a magnetic field. The fractional quantum anomalous Hall effect, as it was dubbed, was initially observed in material called twisted molybdenum ditelluride (MoTe2).
Then, in February this year, an MIT team led by physicist Long Ju spotted the same effect in pentalayer moiré graphene. This material consists of a layer of a two-dimensional hexagonal boron nitride (hBN) with five layers of graphene (carbon sheets just one atom thick) stacked on top of it. The graphene and hBN layers are twisted at a small angle with respect to each other, resulting in a moiré pattern that can induce conflicting properties such as superconductivity and insulating behaviour within the structure.
Answering questions
Although Ju and colleagues were the first to observe the fractional quantum anomalous Hall effect in graphene, their paper did not explain why it occurred. In the latest group of studies, other scientists have put forward a possible solution to the mystery.
According to MIT’s Senthil Todadri, the effect could stem from the fact that electrons in two-dimensional materials like graphene are confined in such small spaces that they start interacting strongly. This means that they can no longer be considered as independent charges that naturally repel each other. The Johns Hopkins team led by Ya-Hui Zhang and the Harvard/Berkeley team led by Ashvin Vishwanath and Daniel E Parker came to similar conclusions, and published their work in Physical Review Letters alongside that of the MIT team.
Crystal-like periodic patterns form an electronic “flat” band
Todadri and colleagues started their analyses with a reasonably realistic model of the pentalayer graphene. This model treats the inter-electron Coulomb repulsion in an approximate way, replacing the “push” of all the other electrons on any given electron with a single potential, Todadri explains. “Such a strategy is routinely employed in quantum mechanical calculations of, say, the structure of atoms, molecules or solids,” he notes.
The MIT physicists found that the moiré arrangement of pentalayer graphene induces a weak electron potential that forces electrons passing through it to arrange themselves in crystal-like periodic patterns that form a “flat” electronic band. This band is absent in calculations that do not account for electron–electron interactions, they say.
Such flat bands are especially interesting because electrons in them become “dispersionless” – that is, their kinetic energy is suppressed. As the electrons slow almost to a halt, their effective mass approaches infinity, leading to exotic topological phenomena as well as strongly correlated states of matter associated with high-temperature superconductivity and magnetism. Other quantum properties of solids such as fractional splitting of electrons can also occur.
“Mountain and valley” landscapes
So what causes the topological flat band in pentalayer graphene to form? The answer lies in the “mountain and valley” landscapes that naturally appear in the electronic crystal. Electrons in this material experience these landscapes as pseudo-magnetic fields, which affect their motion and, in effect, do away with the need to apply a real magnetic field to induce the fractional Hall quantization.
Fractional quantum Hall state appears in ultracold atoms
“This interaction-induced topological (‘valley-polarized Chern-1’) band is also predicted by our theory to occur in the four- and six-layer versions of multilayer graphene,” Todadri says. “These structures may then be expected to host phases where electron fractions appear.”
In this study, the MIT team presented only a crude treatment of the fractional states. Future work, Todadri says, may focus on understanding the precise role of the moiré potential produced by aligning the graphene with a substrate. One possibility, he suggests, is that it simply pins the topological electron crystal in place. However, it could also stabilize the crystal by tipping its energy to be lower than a competing liquid state. Another open question is whether these fractional electron phenomena at zero magnetic field require a periodic potential in the first place. “The important next question is to develop a better theoretical understanding of these states,” Todadri tells Physics World.
