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Photon–photon collisions could shed light on physics beyond the Standard Model

A new way of studying matter that is created when photons collide has been developed by CERN’s Compact Muon Solenoid (CMS) collaboration. Their experiment, done on the Large Hadron Collider (LHC), sheds new light on a mystery surrounding the nature of high-energy collisions between heavy ions. While the team’s results are consistent with the expectations of the Standard Model of particle physics, they hope that further observations could lead to observations that could challenge our conventional understanding of physics.

When a high-energy photon collides with matter it will often transform into an electron–positron pair – a process that involves the energy of the massless photon being converted into the masses of the pair. A similar conversion occurs when heavy ions are smashed together at high energies at facilities like the LHC. These ions are surrounded by clouds of photons and when these photons collide with each other, they can also produce pairs of particles.

In the past few years, Shuai Yang at Rice University and colleagues on the STAR collaboration have been studying these energy-to-mass conversions using the Relativistic Heavy Ion Collider (RHIC) at Brookhaven National Laboratory in the US.

Quark–gluon plasma

A primary aim of RHIC is to smash ions together to create a “quark–gluon plasma” (QGP), which is an extremely hot state of matter in which quarks and gluons, normally stringently bound within nucleons, have enough energy to exist independently. Much to the surprise of Yang and colleagues, it appeared that particles produced by photon–photon collisions affect the properties of the QGP. This was not expected because the photon–photon collision process and the particles in produces are governed by the electromagnetic force, which is much weaker than the strong force that mediates the QGP.

To explore this effect in more detail, the CMS collaboration (which includes Yang) has studied “ultraperipheral” heavy ion collisions at the LHC. These collisions occur when ions narrowly miss each other but pass close enough for their photon clouds to collide. The closer the near miss, the more likely it is that the ions will be excited into higher energy states and then decay by emitting neutrons. Detecting these neutrons provides the team with an accurate measure of ion separation distances.

In the photon–photon collisions that resulted, muon–antimuon pairs are generated and the particles typically fly off in opposite directions. As the ion separation distances became smaller, the CMS team found that the angular distribution of the particles was affected by quantum interference between the photons prior to the collision – something that is predicted by the Standard Model of particle physics. According to Yang, this interference is enhanced at smaller separation distances because close proximity cause the photon clouds to move away from their host ions in directions perpendicular to the ion beams.

According to the researchers, this effect can explain most of the QGP anomalies mass first measured by the STAR collaboration. However, Yang and his CMS colleagues believe that future observations of these photon collisions could reveal that the anomalies are related to new physics beyond the Standard Model, which would be a ground-breaking observation.

The research is described in Physical Review Letters.

The opportunities and challenges of doing science in China

Roberto Soria

How did you end up working in China?

I was born in Italy and did a PhD in astrophysics at the Australian National University. In 2004 I moved to the Harvard-Smithsonian Center for Astrophysics before heading to University College London in 2008. In 2011 I returned to Australia to work at Curtin University and in 2017 moved to China to the University of Chinese Academy of Sciences (UCAS) in Beijing. There I work on several projects and also collaborate with colleagues worldwide. 

Why did you decide to move to China?

When my contract with Curtin University was coming to an end, I assessed my options. Liu Jifeng from the National Astronomical Observatories (NAOC) in Beijing, whom I had met when I was at the Harvard-Smithsonian Center for Astro-physics, encouraged me to come to China and apply for a tenured position at UCAS. I already had some connections in China as I had been regularly visiting Tsinghua University between 2008 to 2010 thanks to a programme called China-UK Fellowship for Excellence. So, it was not like jumping into a completely different universe.

What are your main research areas?

I work on the physics of accretion onto compact objects. For example how a neutron star or black hole receives mass from a nearby star or other sources of gas. I explore how the gas falls towards or into the compact object, how much radiation is emitted, how much mechanical energy is carried by outflows and transferred to the host galaxy, and what is the maximum power that can be generated by such sources. I use X-ray, optical and radio data, and work with different groups that specialize in various areas.

Does that involve international collaboration?

I spend about 30% of my time collaborating with scientists at NAOC and the Institute of High Energy Physics in Beijing. The rest of my time is spent with colleagues in Australia, the US, France and Italy. I’m now part of the $300m SiTian “Sky Monitoring” project, which is a proposed Chinese network of dozens of 1 m-class telescopes in different parts of the world to scan and monitor the whole sky every night. It aims to detect gravitational-wave events, fast radio bursts, or supernovae on the largely unknown timescales of less than one day. We hope to get the project approved in the 15th National Mega-Project Five-Year Plan (2026–2030). Construction could then start in 2026, with facilities operational by 2032.

What are some advantages of working long-term in China as a researcher?

Science has a good social status here. For instance, I was surprised to see pictures of the FAST telescope used as one of China’s landmarks along with the Great Wall and the Forbidden City. That is rare from a western perspective. The level of scientific and technical knowledge in the media is very good in China – the public seem to have a good understanding of science. The money available for building scientific infrastructures is also attractive: telescopes, space missions and so on. You feel that there is interesting science going on and there are opportunities for the future. There are always new missions and facilities to look forward to and you can also think of new topics of research, new ideas and new collaborations.

What’s the biggest challenge?

For me it is the language barrier. I can learn how to buy food or talk to a taxi driver, but it is very difficult to reach the level of Chinese sufficient to participate in technical discussions. Most scientific meetings here are in Chinese, which means that I am often excluded from the astronomy community. For example, the annual conference of the Chinese astronomy community is in Chinese and I was not even invited last year as it would have been a waste of time for me to fly to Shanghai to attend a meeting in which I could not understand any of the discussions. Also, PhD theses must be written in Chinese so it is hard for me to supervise students. Language is important, because it is difficult to do good research if you must spend half of your time trying to communicate with PhD students, postdocs, or even senior professors.

How have you dealt with the pandemic?

When the travel ban was first introduced in February 2020, I was in South Africa for a conference and then went to the University of Sydney, where I have an honorary associate position. I only had a small bag of summer clothes with me. Luckily, I got on a plane before all international flights were shut and made it back to China. I saved my belongings and my job! During the pandemic, I spent time visiting new places in Beijing. I went hiking several times on the Western Hills. I also had the chance to visit Sun Yat-sen University in southern China, where they are developing satellites to detect gravitational waves. I stayed in touch with my parents in Italy via Skype. Luckily, they have been in good health. I do not know what I would do if they needed my immediate assistance.

What do you think of the Chinese government’s pandemic response?

I think China has managed the pandemic pretty well. It avoided an economic recession, which is now badly affecting western Europe. There was no social unrest or dissatisfaction with the government. Lockdowns and restrictions in Europe and the US were often imposed by local governments without co-ordination, which created chaos.

Tell us about your meeting earlier this year with Li Keqiang, the Chinese Premier

I was selected as one of the two speakers to give a 10-minute presentation at the foreign experts’ symposium, which is a meeting between the -Chinese Premier and 30–40 foreign academics working in China. My speech was about the need to keep open channels for collaborations with foreign countries because it is necessary for us to do research at the international level. I mentioned China’s long history of international exchanges, to present-day multinational collaborations on projects such as the FAST telescope.

Premier Li Keqiang was very sympathetic. I think he had seen the texts of our presentations beforehand and his comments were much to the point. Of course, we couldn’t shake hands due to COVID restrictions, but it was nice to be sitting next to him. It was also a good opportunity to get to know other foreigners here, including someone who teaches Latin in Beijing and is originally from Turin like me.

What are your future plans?

I would like to return to Italy eventually. It is hard to remain in China where I don’t speak the language well enough and I’m always a visible minority. However, my retirement plans are still a long way off and I think I can still contribute to China’s science and perhaps later as an overseas collaborator.

I want to continue developing international projects from the Chinese side and in the longer term explore the possibility of continuing to work for UCAS, but be based at least half of my time closer to my family or to some of my other scientific collaborators.

Is this international approach something that institutions in China could do more of?

I think it would be important for UCAS and the Chinese Academy of Sciences (CAS) to think of themselves more like an international brand that can open research offices and support scholars based in other countries. In fact, the CAS has already started doing that with CAS South America Center for Astronomy in Chile. Moreover, the presence of many second-generation Chinese immigrants in western countries is an untapped market for the possible opening of Chinese university campuses overseas.

Monolayer strain sensor sets new record

A new atomically-thick strain sensor is 100 times more sensitive than commercial devices and 10 times more sensitive than alternative versions based on graphene. According to its developers at China’s Peking University, the prototype device, which is made from tungsten diselenide, could be used to make a new generation of electronic skin.

Tungsten diselenide (WSe2) belongs to a family of crystals known as transition metal dichalcogenides (TMDCs). These two-dimensional, van der Waals layered materials have the chemical formula MX2, where M is a transition metal such as molybdenum or tungsten and X is a chalcogen such as sulphur, selenium or tellurium.

In their bulk form, TMDCs act as indirect band-gap semiconductors. When scaled down to monolayer thicknesses, however, they behave as direct band-gap semiconductors, capable of absorbing and emitting light at high efficiencies. This property means that TMDCs in their 2D form are attractive building blocks for devices such as light-emitting diodes, lasers, photodetectors and solar cells. They could also be used to make circuits for low-power electronics and sensors. And unlike bulk semiconductors, which are usually brittle, TMDCs are able to withstand in-plane strains as high as 11%, which makes them promising materials for flexible electronic devices and strain sensors.

Nonlinear Hall effect

Researchers recently found that strain significantly affects the physical properties of TMDCs because it induces a form of magnetization when an electric field is applied. The result is a nonlinear version of the anomalous Hall effect in which the magnetic field exerts a sideways force on the material’s electrons, leading to a voltage difference proportional to the strength of the magnetic field and the longitudinal electric field. This is different from the conventional Hall effect, which occurs when electrons flow through a conductor only when an external magnetic field is present. The voltage produced also scales quadratically with the strength of the longitudinal electric field, in the absence of an external magnetic field, rather than linearly.

This type of Hall effect occurs when a Hall current is generated in response to a “second-order” component, which is related to the electrons’ orbital magnetism (that is, the magnetization induced by the particles’ orbital motion, rather than that caused by their spin), due to an applied electric field. It means that the charge carriers in a current travelling along a material can be deflected – thereby producing a Hall voltage without an externally applied magnetic field.

In 2019, researchers observed the nonlinear Hall effect for the first time in few-layer tungsten ditelluride, WTe2, a material that also belongs to the TMDC family of materials. Then, earlier this year, a team led by Zhi-Min Liao of Peking University’s School of Physics found it in a monolayer WSe2 when the material is strained along its crystalline axis.

Strain-resistance experiments

In the latest work, which the team report in Chinese Physics B, the researchers decided to investigate this effect further by studying how the resistance of WSe2 changes when strain is applied along the material’s crystalline axis. They performed their experiments on flakes of WSe2 obtained by shaving off monolayer-thin slivers from bulk crystals of the material. To apply strain in the direction they wanted, they selected flakes with long, straight edges and transferred these onto a single crystal piezoelectric substrate (PMN-PT). After they had aligned the WSe2 flakes along the [001] orientation of the PMN-PT crystal, they attached external electrodes to the flakes so that they could apply a voltage to the crystal to generate a piezoelectric displacement and induce strain in the WSe2 flakes in this direction.

By controlling the amount of strain applied, the team observed a so-called Berry curvature dipole, which is a quantum mechanical property that dictates how moving charges (such as electrons) propagate through solid semiconductors. With increasing strain, this Berry curvature dipole can generate an orbital magnetization, which decreases electron mobility and thus increases the material’s resistance. The researchers found that this resistance strongly depends on the strain applied in monolayer WSe2 at various temperatures and that the strain gauge factor (the ratio of the relative change in a material’s resistance to its mechanical strain – a key parameter of strain sensors) is as high as 2400 at 2 K.

The new work shows that the performance of strain sensors can be effectively improved by modulating the Berry curvature by changing the strain applied to 2D van der Waals materials like WSe2. “The technique should allow us to make highly sensitive strain sensors and flexible electronics,” Liao says. “The atomically-thick material is also easy to integrate into various nanodevices, which could be useful for nanoelectromechanical systems (NEMS),” he tells Physics World.

Life beyond the Nobel: Takaaki Kajita and the hunt for gravitational waves

For the past half a century, Japan has led the world in neutrino science. In the 1980s the Japanese physicist Masatoshi Koshiba masterminded the construction of a huge neutrino detector located 1000 m underground in a lead and zinc mine in Japan in Hida, Gifu Prefecture. Called Kamiokande, it was an enormous water tank surrounded by photomultiplier tubes to detect the flashes of light produced when neutrinos interacted with atomic nuclei in water molecules.

Koshiba famously used the experiment to detect neutrinos from a distant supernova explosion – in the process becoming one of the founders of neutrino astronomy. The work led him to sharing the 2002 Nobel Prize for Physics for the detection of cosmic neutrinos.

Takaaki Kajita

Takaaki Kajita – who was still a physics student when Koshiba did his Nobel-prize-winning work – was intrigued by the study of these ghostly particles and decided to carry out a PhD at the University of Tokyo under the supervision of Koshiba. The work fascinated him enough such that in 1988, Kajita joined the Institute for Cosmic Ray Research (ICRR) at the University of Tokyo where he spent the next two decades working on neutrino physics.

In 1996, Kamiokande’s successor – the Super-Kamiokande experiment – began operation and two years later, Kajita played a key role in using the facility to show that the ratio of electron to muon neutrinos coming from opposite sides of the Earth were different. This meant that these neutrinos – created when cosmic rays interact with nuclei in the upper atmosphere – were changing flavour as they passed through the Earth. This showed, for the first time, that neutrinos must have mass, albeit at only about 0.1 eV.

Science has become so important for deciding the direction of society – or even the future of the Earth

For the work, Kajita followed in Koshiba’s footsteps and in 2015 shared half that year’s physics Nobel with the neutrino physicist Arthur McDonald “for the discovery of neutrino oscillations, which shows that neutrinos have mass”. Experiments at the Sudbury Neutrino Observatory (SNO), led by McDonald, determined how many of the electron neutrinos produced in the Sun change into muon neutrinos or tau neutrinos as they travel to the Earth. SNO data were able to confirm the fact that about two-thirds of the solar electron neutrinos change flavour by the time they reach the Earth.

Switching fields

Despite adding to Japan’s rich legacy in neutrino physics, in 2008 – before Kajita was awarded the Nobel prize – he made a bold decision to switch research fields. “After many years of neutrino research, I wanted to do something new that would be important and exciting,” Kajita told Physics World. “Fortunately, our institute had been planning a gravitational-wave project as the next major project to come after Super-Kamiokande.” That facility was the KAGRA gravitational-wave observatory, which would be based underground nearby Super-Kamiokande.

Kajita became director of ICRR in 2008 and played a major role in getting KAGRA funded and constructed. KAGRA is a huge interferometer in which a laser beam is split down two 3 km-long arms. The beams are reflected multiple times between mirrors suspended at the ends of each arm and then combined at a detector. A gravitational wave is a ripple in space–time and when it passes through an interferometer, it can change the distances between the mirrors. This is detected as a change in how the laser light interferes at the detector.

Construction of KAGRA, which is based 200 m underground, began in 2010 and became operational in 2020. Given the impact of COVID-19, KAGRA is expected to join the international hunt for gravitational waves next year. Kajita is currently the project’s principal investigator.

As well as switching research fields, Kajita also delved into other aspects of science, becoming a member of the Science Council of Japan (SCJ) in 2017. The role of the SCJ is to make recommendations to the government and wider society about certain issues. In 2020 he was nominated by the other SCJ members as its president. “I do not know why many of them voted to me,” admits Kajita. “But I guess that the Nobel prize had some influence on the vote!”

Kajita says he joined the SCJ to communicate the importance of basic science to the public and indicates that can be as important as doing the science itself. “Science has become so important for deciding the direction of society – or even the future of the Earth,” he says. “Physics is clearly one of the important parts of science. So I hope that physicists dedicate their time for other activities such as science policy.”

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Physics World‘s Nobel prize coverage is supported by Oxford Instruments Nanoscience, a leading supplier of research tools for the development of quantum technologies, advanced materials and nanoscale devices. Visit nanoscience.oxinst.com to find out more.

Tackling the big questions in physics with Jim Al-Khalili, how a physicist worked out why dinosaurs went extinct

In this episode of the Physics World Weekly podcast I chat with the physicist, author and broadcaster Jim Al-Khalili about his new television documentary Jim Al-Khalili’s Guide to Life, The Universe and Everything, his fascination with the quantum world and his long running BBC radio series The Life Scientific.

Muons are elementary particles that have proven to be very useful for studying the properties of materials, as Peter Baker of the UK’s ISIS Neutron and Muon Source explains. Baker talks about how muons are made at the Oxfordshire facility and how they are used to study a range of things including new battery designs, superconductors and quantum decoherence.

The 2021 Nobel Prize for Physics will be awarded on Tuesday, 5 October and in the run up to the announcement our “Life beyond the Nobel” series looks at Nobel laureates who have shifted gears after bagging their prizes. Physics World’s Laura Hiscott joins me to talk about the amazing career of Luis Alvarez, who solved the mystery of why dinosaurs went extinct 66 million years ago after winning a Nobel in 1968 for his work on particle detection.

Oxford Instruments Logo 2021

Physics World‘s Nobel prize coverage is supported by Oxford Instruments Nanoscience, a leading supplier of research tools for the development of quantum technologies, advanced materials and nanoscale devices. Visit nanoscience.oxinst.com to find out more.

New dawn for South African radio astronomy as major telescope nears completion

A $25m radio telescope in South Africa that is dedicated to observing the early universe is expected to be complete early next year. Nearly six years after construction began, the remaining dozen 14 m-diameter dishes belonging to the Hydrogen Epoch of Reionization Array (HERA) will be installed over the coming months. It will then aim to study the first galaxies and black holes in the universe.

The signal we are trying to detect has travelled over 13 billion light-years to reach us, so we need a big telescope in order to receive enough signal to detect it

David DeBoer

Funded by several institutions as well as the US National Science Foundation, the Gordon and Betty Moore Foundation, HERA is situated next to MeerKAT in the arid Karoo region, near Carnarvon in the Northern Cape province. Using a 350 antenna-array of 14 m dishes, HERA’s primary science goal will be studying the “Epoch of Reionization”. This occurred about 13 billion years ago when the universe was still young and is the period when the first stars and galaxies formed.

The first billion years of cosmic history are shrouded in mystery and the shroud only began to lift when ultraviolet light from the first stars and galaxies ionized the fog of neutral hydrogen gas that filled the universe. HERA will allow scientists to probe this epoch directly.

HERA currently has the best sensitivity to measure the tiny radiation emitted from hydrogen atoms that is used to observe the epoch and this month HERA released the first set of observations in 2017–2018 using about 50 dishes.

“The signal we are trying to detect has travelled over 13 billion light-years to reach us, so we need a big telescope in order to receive enough signal to detect it,” says David DeBoer, HERA project manager and an astronomer at the University of California, Berkeley. “The data taken to-date with the first antennas is allowing us to place some limits, but not actually detect our elusive signal. When done, and when we’ve sufficiently understood the complex details, we expect to detect the signal over may times and many different spatial scales.”

Dawn of an HERA

When complete, HERA will have enough collecting area to quickly detect this signal from far away in the universe. The full HERA array will also be able to probe the universe even further back in time before the stars started to ionize the universe, known as the “cosmic dawn”.

“It will tell us something fundamental about the initial processes of star formation and about cosmology in the early universe, just a mere hundreds of million years after the Big Bang,” says Mario Santos of the University of Western Cape and the South African Radio Astronomy Observatory, who sits on HERA’s board. “But such detection will require very sophisticated signal processing and analysis techniques as well as lots of computing power that are being developed hand in hand with construction of the telescope.”

South Africa currently has several research groups that are working on HERA’s data and its theoretical interpretation. “As we are able, we will make the data public and provide some tools for its use,” says DeBoer.

Hyperbaric oxygen therapy could slow, or even reverse, Alzheimer’s disease pathology

Hyperbaric oxygen therapy (HBOT), an established medical treatment that involves breathing pure oxygen in a pressurized environment, could provide a new means to slow the progression, or even prevent the development, of Alzheimer’s disease. That’s the conclusion of a new study from researchers at Tel Aviv University and Shamir Medical Center.

Reporting their findings in Aging, the researchers demonstrate that HBOT can improve cerebral blood flow and cognitive function in mouse models of Alzheimer’s disease, as well as in elderly patients with significant memory loss. They also show for the first time that HBOT can reduce the volume of amyloid plaques in these mouse models. As amyloid plaques are one of the main hallmarks found in the brains of people with Alzheimer’s disease, this gives hope for similar improvements in Alzheimer’s disease patients.

Reduced cerebral blood flow, and the resulting decrease in oxygen supply to the brain (hypoxia) is associated with the onset of dementia and correlates with the degree of cognitive impairment in Alzheimer’s disease. The team hypothesized that developing a technique to target vascular dysfunctions, such as reduced vessel diameters, may offer a way to treat Alzheimer’s disease – a disorder for which there is presently no effective intervention.

Animal investigations

The researchers first examined the impact of HBOT on 5XFAD transgenic mice, which have impaired cognitive abilities. They exposed the mice to HBOT at twice atmospheric pressure for 60 min per day, 20 times over four weeks. Post-mortem staining revealed a significant reduction in amyloid burden in the hippocampus of treated mice, with fewer and smaller plaques than seen in control untreated 5XFAD mice.

Two-photon microscopy of amyloid plaques

The team also performed two-photon microscopy imaging in live animals to study the dynamics of amyloid plaque formation. Without treatment, pre-existing plaques increased in size over time, with smaller plaques growing the most.

HBOT halted the growth of these small plaques and reduced the volumes of medium-sized and large plaques. Overall, existing plaques in control mice grew by an average of 12.3% over one month, while plaques in treated mice shrank by 40.05% on average.

Using HBOT to increase oxygen delivery to the brain also prevented the formation of new plaques. Over one month, the number of plaques seen in untreated mice almost doubled, while in mice receiving HBOT the number remained constant. Live animal imaging also revealed that HBOT alleviated the reduction in vessel diameter seen in Alzheimer’s disease mice, leading to increased cerebral blood flow and reduced hypoxia.

Finally, the researchers investigated whether these physical responses to HBOT affected the behavioural performance of the mice. They found that HBOT improved the animals’ nest construction abilities and exploratory behaviour, compared with control mice. In addition, control mice showed a decreased spatial recognition and contextual memory performances over time, which was not seen in treated animals.

“We have discovered for the first time that HBOT induces degradation and clearance of pre-existing amyloid plaques – treatment, and stops the appearance of newly formed plaques – prevention,” explains corresponding author Uri Ashery in a press statement.

Clinical study

Motivated by these findings, Ashery, co-author Shai Efrati and colleagues treated six elderly patients with significant memory loss with 60 HBOT sessions over three months. Each session included breathing 100% oxygen via a mask at twice atmospheric pressure for 90 min, with 5 min breaks every 20 min. High-resolution MR imaging before and after HBOT revealed that this treatment improved cerebral blood flow in several brain areas, with increases of 16–23%.

The team employed computerized cognitive tests to evaluate the subjects’ cognitive functions before and after HBOT. At baseline, patients attained a mean global cognitive score of 102.4±7.3 (a score of 100 represents the average in their age group), and a lower mean memory score of 86.6±9.2. HBOT improved both measures, increasing the global cognitive score to 109.5±5.8 and the mean memory score to 100.9±7.8.

“Elderly patients suffering from significant memory loss at baseline revealed an increase in brain blood flow and improvement in cognitive performance, demonstrating the potency of HBOT to reverse core elements responsible for the development of Alzheimer’s disease,” says Efrati.

The researchers conclude that the mouse model findings – combined with the similar effects observed in patients – suggest that HBOT causes structural changes in blood vessels, which serve to increase cerebral blood flow, reduce brain hypoxia and improve cognitive performance. They note that HBOT holds promise for the prevention of Alzheimer’s disease as it not only addresses the symptoms, but targets the core pathology and biology responsible for the advancement of the disease.

‘Most perfect graphene ever’ grows fold-free on metal foil

A team of researchers in Korea claims to have synthesized the most perfect large-area single-crystal graphene film ever by pinning down the temperature above which unwanted folds naturally develop in the carbon sheet. The new fold-free film will likely be used to make high-performance electronic and photonic devices.

Pure samples of graphene (a sheet of carbon just one atom thick) are usually grown using chemical vapour deposition (CVD). In this technique, a metal substrate is allowed to react under vacuum with volatile carbon-containing precursor chemicals, and a thin layer of pure carbon forms on its surface. While CVD is good for making high-quality graphene sheets with relatively large areas (a few centimetres on a side), the resulting samples generally contain some imperfections. These can include grain boundaries, regions with additional layers (adlayers), wrinkles and folds, all of which can degrade the material’s performance.

Compressive stress is the culprit

For scientists in search of ultrapure graphene, wrinkles and folds have proven especially tough to eliminate. These imperfections arise from the compressive stress created by the thermal contraction of the metal substrate on which the graphene is grown. As the materials cool down after the high-temperature CVD process is complete, this stress is partially released, and the resulting “de-adhesion” process produces wrinkles and folds in certain regions of the graphene.

Previously, researchers led by Rod Ruoff from the Center for Multidimensional Carbon Materials (CMCM) at the Institute for Basic Science within the Ulsan National Institute of Science and Technology (UNIST) in Korea discovered folds even in adlayer-free graphene grown on single crystalline copper metal foils. Their measurements showed that these folds are three-layered structures in the graphene sheet that vary in width from ten to hundreds of nanometres. They form parallel to each other at separations of about 50 to 100 microns, and sometimes run for centimetres in length.

While some researchers have reported obtaining graphene without folds – by, for example, using metal film substrates with a lower coefficient of thermal expansion – no group had achieved fold-free graphene films on metal foil substrates. The distinction between foil and film is important because metal foils have many advantages over conventional metal films: they are cheaper; easy to scale up to larger sizes and can be grown by stacking many of them in parallel over a single growth run.

Restricting the growth temperature

Ruoff and colleagues now say that they have produced large areas of single-crystal, fold-free monolayer graphene films on a metal foil substrate by restricting the temperature at which the material is grown to between 1000 K and 1030 K. To do this, they performed a series of experiments in which they used a mixture of ethylene with hydrogen in a stream of argon gas as the precursor to grow graphene on copper-nickel (Cu-Ni) foils developed in their laboratory. By repeating this process at different temperatures (including 1020 K), they determined the temperature at which folds form.

The researchers then used a technique called low-energy electron diffraction (LEED) to show that their fold-free graphene films form as single crystals over the entire growth substrate because they have a single orientation over a large area. They supplemented their LEED results with several other measurements, including transmission electron microscopy performed by UNIST graduate student Myeonggi Choe, a member of Zonghoon Lee’s group at UNIST, to confirm the presence of large area, single crystal, fold-free graphene.

Single crystal with essentially no imperfections

To test the electronic properties of the new material, the team prepared field-effect transistors (G-FETs) from it and found that the devices boasted very high electron and hole mobilities (around 7 × 103 cm2/V/s). Importantly, they observed that the G-FETs could be configured in any direction and at any location within the graphene sheet, with the mobilities of all the G-FETS remaining remarkably similar – a feat not achieved with other graphene films to date. “Such remarkable performance is possible because the fold-free graphene film is a single crystal with essentially no imperfections,” says team member and UNIST graduate student Yunqing Li, who was responsible for this part of the study.

The researchers also showed that they could grow their graphene on five foils (measuring 4 × 7 cm) at once, with each foil yielding two identical pieces of high-quality fold-free film on both sides of the foil. The graphene can then be removed, or delaminated, from the foils in about a minute using a technique called electrochemical bubbling transfer and the Cu-Ni foils can quickly be readied for a new growth/transfer cycle, says team member and UNIST graduate student Meihui Wang. Indeed, Wang found that the team’s 80:20 Cu-Ni(111) foils can be reused over and over once the graphene has been removed from them.

Study co-author Da Luo and colleagues say their high-quality material could be used to make advanced devices with improved electronic properties. “The fold-free sheets can likely also be stacked more easily – either with themselves or sheets made from other two-dimensional materials, something that could further the range of potential applications,” they conclude.

The team, which reports its work in Nature, is now undertaking further studies with this graphene. “We expect to report on these experiments after more is learned,” Ruoff tells Physics World.

Life beyond the Nobel: Brian Josephson and his interest in the mind

With a Nobel prize under your belt and unshackled by the need to “prove” yourself, it must be tempting to set off in new directions – to try your hand at topics beyond the area in which you originally made your name. One Nobel-prize-winning physicist who has perhaps veered off the conventional path more than any other is Brian Josephson, who leads the self-styled Mind-Matter Unification Project at the University of Cambridge in the UK. It aims to understand “from the viewpoint of the theoretical physicist, what may loosely be characterized as intelligent processes in nature, associated with brain function or with some other natural process”.

In other words, Josephson, 81, spends his days thinking about how the brain works, investigating topics such as language and consciousness, and pondering the fundamental connections between music and the mind. Most controversially, as far as physicists are concerned, he also carries out speculative research on paranormal phenomena, a field known as parapsychology. Josephson’s interests even touch on homeopathy and cold fusion – two areas in which few physicists would dare to dabble.

Photo of Brian Josephson

But Josephson’s interest in consciousness and the mind is nothing new. In fact, it began long before his Nobel Prize for Physics, which he won in 1973 for work done in the early 1960s during his PhD at the Cavendish Laboratory, Cambridge. Under the supervision of Brian Pippard, Josephson had predicted that a superconducting current can tunnel through an insulating junction, even when there is no voltage across it, with the current oscillating at a well-defined frequency when a voltage is applied (Phys. Lett. 7 251). Such “Josephson junctions” are central to superconducting quantum interference devices (SQUIDs), which can measure magnetic fields with exquisite sensitivity.

But almost as soon as his PhD was over, Josephson’s attention quickly switched elsewhere. During a year-long postdoc at the University of Illinois at Urbana-Champaign, John Bardeen (still the only person ever to have won two Nobel physics prizes) tried to persuade Josephson to continue his work in on superconductivity. Unconvinced, he decided to work instead with Leo Kadanoff on critical phenomena. “But after that I felt that the easier and more interesting aspects of many-body theory had been done and I started trying to understand brain function,” Josephson says.

I felt that the easier and more interesting aspects of many-body theory had been done and I started trying to understand brain function

Brian Josephson

His interests were piqued further after returning to Cambridge, when Josephson got to know the mathematical geneticist George Owen, who in his spare time investigated poltergeist claims. “He talked to me about parapsychology generally and got me interested in that, particularly as I could see parallels between psi phenomena and quantum mechanics,” Josephson recalls. In 1974, shortly after picking up his Nobel prize in Stockholm, Josephson was invited by Owen to a conference on “psychokinesis” in Toronto, where he saw demonstrations of metal bending. “I did some research on this but have always regarded it as a sideline,” Josephson says.

Still, Josephson’s new line of interest was clearly established. He went on to give a course on “creative intelligence” at the Cavendish and even collaborated with Hermann Hauser – the physicist and technology entrepreneur who helped set up Acorn Computers – on a paper on the logic of developmental processes. As the years went by, Josephson began getting invited to conferences concerned with mind processes. “I then started trying to link concepts such as semiosis with quantum physics. Currently I’m working with a quantum physicist who is developing the maths side,” he says.

Looking back on his career, Josephson thinks he would have moved into studying the mind even if he had never received his Nobel prize. “Having tenure would probably have given me freedom to work on it,” he says. Still, despite the prestige that a Nobel brings, life outside the mainstream has not been easy. “The Nobel prize didn’t stop the department being very hostile,” Josephson claims, citing incidences of potential collaborators being discouraged from working with him and having their promised funding withdrawn.

Recognition that mind is fundamental rather than matter will be as significant step for physics as the step from classical to quantum physics.

Brian Josephson

He has also faced criticism from the likes of geneticist David Winter, who have accused him of suffering from “Nobel disease” – the notion that a Nobel prize gives a scientist who is an expert in one area an “unfounded confidence” to speak on subjects they know nothing about. Winter believes the affliction encourages sufferers to “spout anti-scientific rubbish”, citing the Nobel-prize-winning chemist Linus Pauling who thought that high doses of vitamin C are medicinally useful.

Such comments do not seem to deter Josephson, who believes that, on the contrary, it’s his critics who are in the dark. “It is people such as Winter who speak with unfounded confidence, on subjects they know essentially nothing about such as telepathy, or memory of water,” he insists. “In the latter case, fallacious arguments are frequently used to dismiss the possibility.”

Indeed, Josephson told Physics World he thinks his present work is “much more important than my superconductivity work” even though it has not been finalized. “The point is that recognition that mind is fundamental rather than matter will be as significant step for physics (and for science generally) as the step from classical to quantum physics,” he says. “A number of people have asserted this in the past of course and the question is when we will reach the ‘tipping point’ when ’the club’ will start to take note?”

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From order to disorder: NMR insights into ionic conduction in battery materials

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The development of next-generation solid-state ion conductors hinges on an understanding of microscopic diffusion mechanisms and the identification of roadblocks along macroscopic diffusion pathways (e.g. intragrain defects and grain boundaries). At the microscopic scale, ion conduction relies on transient short-range interactions between the diffusing and framework ions, and on the connectivity of the diffusion sites, hence, on the local structure and composition.

Two common assumptions in the design of solid electrolytes are that: 1) the absence of planar defects in the bulk of crystalline inorganic electrolytes; and 2) rapid polymer chain rearrangements (segmental motion) in polymer electrolytes; are required for fast ion diffusion. Yet, our recent work on Li- and Na-ion conducting rock salt halide electrolytes and polymeric ionic liquids demonstrates that these rules are relaxed for specific composition-structure combinations, such that fast ion diffusion on the order of mS/cm can be obtained in rock salt halides containing a significant fraction of planar defects, and in semi-crystalline polymeric ionic liquids.

Using a combination of electrochemical impedance spectroscopy (EIS), solid-state nuclear magnetic resonance (ssNMR), pulsed field gradient NMR (PFG-NMR), NMR relaxometry, and first principles calculations, we provide a multiscale understanding of ion diffusion processes and link these findings to local structure features, crystallinity and materials synthesis/processing conditions.

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Raphaële Clément is an assistant professor in the materials department at the University of California, Santa Barbara (UCSB), US. She received her PhD in chemistry in 2016 from the University of Cambridge, UK, working under the supervision of Prof. Clare Grey. Her doctoral work focused on the study of layered sodium transition metal oxide cathodes for Na-ion secondary batteries. She then joined Prof. Gerbrand Ceder’s group at the University of California, Berkeley (UC Berkeley), US, focusing on cation-disordered rock salt oxyfluorides for Li-ion battery applications. She joined the UCSB faculty in 2018. Her primary research focus is the development and implementation of magnetic resonance techniques (experimental and computational) for the study of battery materials and beyond, with a strong emphasis on operando tools. She is an Associate Editor for Battery Energy, a new open-access journal by Wiley.




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